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NH 4 + is a N species preferentially consumed by phytoplankton (Nogaro and Burgin, 2014). As both assimilation and nitrification can increase δ 15 N in seawater, both processes could be significant in removing NH 4 + from the water column in the East PRE. 3.3. Nitrification of NH 4 +: a significant source of NO 3 − in the PRE? o d u c t i o n m P o t e n t i a l C o n s u p t i o n Methanol Propylene Ethylene BTX Propylene Oxide Ethylene Oxide 0 20 40 60 80 100 120 140 160 0 50,000 100,000 150,000 G H G E m i s s i o n s (M t C O 2-e q) Production Volume (kt) (a) (b) (c) O H 2 C 2 H 2 C 3 N H 2C N N H 3C O H 2C O OH N + O-O NH 2 H 3 C 3 H 3C CH 3 CH 4 H 3C O HO OH CH 10/13/2016 Samples were washed with PBS and examined under a CLSM to observe green fluorescence . with excitation and emission peak of 495 and 529 nm, respectively. and ***P < 0.001 were considered significant, moderately significant, and highly significant, respectively. NH O S NH O O HN S H N O O HN S N H O O NH Figure S1 Synthesis route of TCPP

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solution of NH. 4. VO. 3. reacts with 506 cm. 3. of sulfur(IV) oxide gas measured at 20.0 °C and 98.0 kPa. Use this information to calculate the oxidation state of the vanadium in the solution after the reduction reaction with sulfur(IV) oxide. Explain your working. The gas constant . R = 8.31 J K –1. mol –1. [6 marks]

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